Catalytically Active Carbon From Cattail Fibers for Electrochemical Reduction Reaction

FABRICATION OF CARBON FIBERS FROM COMMERCIAL WET SPIN POLYACRYLONITRILE FIBERS

Carbon fibers are fabricated from different materials such as special polyacrylonitrile (PAN) fibers, cellulose fibers and pitch. But PAN fibers are recognized as the most widely used precursor for the present-day manufacture of carbon fibers. The process of fabrication carbon fibers from special PAN fibers is composed of two steps including oxidative stabilization at low temperature and carbon...

Electrochemical Reduction of Carbon Dioxide

Single walled carbon nanotube in the reaction layer of gas diffusion electrode for oxygen reduction reaction

In this paper, the effect of surface area of reaction layers in gas diffusion electrodes on oxygen reduction reaction was investigated. For this purpose, various amounts (0.1, 0.2, 0.3, 0.4, 0.5, 1, 1.5 and zero %wt of total loading of reaction layer) of single walled carbon nanotube (SWCNT) were inserted in the reaction layer. The performance of gas diffusion electrodes for oxygen reduction re...

Graphite Carbon-Supported Mo2C Nanocomposites by a Single-Step Solid State Reaction for Electrochemical Oxygen Reduction

Novel graphite-molybdenum carbide nanocomposites (G-Mo2C) are synthesized by a typical solid state reaction with melamine and MoO3 as precursors under inert atmosphere. The characterization results indicate that G-Mo2C composites are composed of high crystallization and purity of Mo2C and few layers of graphite carbon. Mo2C nanoparticles with sizes ranging from 5 to 50 nm are uniformly supporte...

Electrochemical activation of commercial polyacrylonitrile-based carbon fiber for the oxygen reduction reaction.

Nitrogen (N)-doped carbon and its non-noble metal composite replacing platinum-based oxygen reduction reaction (ORR) electrocatalysts still have some fundamental problems that remain. Here the micron-sized commercial polyacrylonitrile-based carbon fiber (PAN-CF) electrode was modified using an electrochemical method, converting its inherent pyridinic-N into 2-pyridone (or 2-hydroxyl pyridine) f...